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Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I)

Catalog Number
ACM854045935
Product Name
Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I)
Structure
Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I)
CAS
854045-93-5
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Synonyms
SC10751; JohnPhos AuCl; [[1,1 inverted exclamation marka-Biphenyl]-2-ylbis(t-butylphosphine]chlorogold; AKOS024259177; Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I), 98%; KS-000019BH; TRA0069872; Chloro[2-(di-t-butylphosphino)biphenyl]gold(I);
IUPAC Name
chlorogold;ditert-butyl-(2-phenylphenyl)phosphane;
Molecular Weight
530.826g/mol
Molecular Formula
C20H27AuClP;
InChI
InChI=1S/C20H27P.Au.ClH/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;;/h7-15H,1-6H3;;1H/q;+1;/p-1;
InChI Key
MZMOUYZCJIFYAH-UHFFFAOYSA-M;
Complexity
302
Covalently-Bonded Unit Count
2
Exact Mass
530.12g/mol
Heavy Atom Count
23
Monoisotopic Mass
530.12g/mol
Rotatable Bond Count
4
Topological Polar Surface Area
0A^2
Application
Highly active gold catalyst for the intramolecular exohydrofunctionalization of allenes.

Catalyst used for the hydroarylation of allenes.

Catalyst used for the intramolecular cyclization of monopropargyl triols.

Synthesis of pyrroles via a gold-catalyzed cascade reaction.

Gold-catalyzed carboalkoxylations of 2-ethynylbenzyl ethers.

Gold-catalyzed annulations of allenes with N-hydroxy anilines.
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