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cBRIDP

Catalog Number
ACM742103271
Product Name
cBRIDP
Structure
cBRIDP
CAS
742103-27-1
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Synonyms
di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine; di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl) phosphine; Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphine cBRIDP; Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphane; SCHEMBL377365; 742103-27-1; di-t-butyl-(2,2-diphenyl-1-methylcyclopropyl)-phosphine; di-t-butyl (2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; (1-Methyl-2,2-diphenylcyclopropyl)di-tert-butylphosphine;
IUPAC Name
ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;
Molecular Weight
352.502g/mol
Molecular Formula
C24H33P;
Canonical SMILES
CC1(CC1(C2=CC=CC=C2)C3=CC=CC=C3)P(C(C)(C)C)C(C)(C)C;
InChI
InChI=1S/C24H33P/c1-21(2,3)25(22(4,5)6)23(7)18-24(23,19-14-10-8-11-15-19)20-16-12-9-13-17-20/h8-17H,18H2,1-7H3;
InChI Key
QMLPJDVGNRHGJQ-UHFFFAOYSA-N;
Complexity
422
Covalently-Bonded Unit Count
1
Exact Mass
352.232g/mol
Heavy Atom Count
25
Monoisotopic Mass
352.232g/mol
Rotatable Bond Count
5
Topological Polar Surface Area
0A^2
Undefined Atom Stereocenter Count
1
Application
Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.

Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.

Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction.
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