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- Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst
Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst
PRICE INQUIRYCatalog Number
ACM863971635-3
Product Name
Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/863971-63-5.gif)
CAS
863971-63-5
Synonyms
863971-63-5;Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II);DTXSID40856225;Ruthenium(2+) hydride (2E)-2-[(di-tert-butylphosphanyl)methylidene]-6-[(diethylamino)methyl]-2H-pyridin-1-ide--carbon monooxide (1/1/1/1);
IUPAC Name
carbon monoxide;N-[[(6E)-6-(ditert-butylphosphanylmethylidene)pyridin-1-id-2-yl]methyl]-N-ethylethanamine;hydride;ruthenium(2+);
Molecular Weight
451.557g/mol
Molecular Formula
C20H35N2OPRu;
Canonical SMILES
[H-].CCN(CC)CC1=CC=CC(=CP(C(C)(C)C)C(C)(C)C)[N-]1.[C-]#[O+].[Ru+2];
InChI
InChI=1S/C19H34N2P.CO.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;/h11-13,15H,9-10,14H2,1-8H3;;;/q-1;;+2;-1/b17-15+;;;;
InChI Key
FGPPOYVQHGYDJC-VHPYDAKRSA-N;
Complexity
439
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
1
Exact Mass
452.153g/mol
H-Bond Acceptor
4
Heavy Atom Count
25
Monoisotopic Mass
452.153g/mol
Rotatable Bond Count
7
Topological Polar Surface Area
5.2A^2
Application
The primary purpose of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst, is to facilitate a variety of chemical transformations, including the direct synthesis of amides from alcohols and primary amines, the hydrogenation of esters producing high yields under mild pressure and neutral conditions, and the dehydrogenative coupling of alcohols to form esters. Furthermore, it is adept at synthesizing amides from esters and amines while liberating hydrogen gas, as well as the hydrogenation of 3-methyl-2-oxazolidinone, showcasing its versatility and efficiency in catalyzing complex reactions.
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