CAS 863971-63-5 Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst

Synonyms

863971-63-5;Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II);DTXSID40856225;Ruthenium(2+) hydride (2E)-2-[(di-tert-butylphosphanyl)methylidene]-6-[(diethylamino)methyl]-2H-pyridin-1-ide--carbon monooxide (1/1/1/1);

IUPAC Name

carbon monoxide;N-[[(6E)-6-(ditert-butylphosphanylmethylidene)pyridin-1-id-2-yl]methyl]-N-ethylethanamine;hydride;ruthenium(2+);

Molecular Weight

451.557g/mol

Molecular Formula

C20H35N2OPRu;

Canonical SMILES

[H-].CCN(CC)CC1=CC=CC(=CP(C(C)(C)C)C(C)(C)C)[N-]1.[C-]#[O+].[Ru+2];

InChI

InChI=1S/C19H34N2P.CO.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;/h11-13,15H,9-10,14H2,1-8H3;;;/q-1;;+2;-1/b17-15+;;;;

InChI Key

FGPPOYVQHGYDJC-VHPYDAKRSA-N;

Complexity

439

Covalently-Bonded Unit Count

Defined Bond Stereocenter Count

Exact Mass

452.153g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

452.153g/mol

Rotatable Bond Count

Topological Polar Surface Area

5.2A^2

MSDS

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COA

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Spec Sheet

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Application

Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.

Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.

Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.

Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.

Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone