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(2-Butenyl)chloropalladium dimer
PRICE INQUIRYCatalog Number
ACM12081220-1
Product Name
(2-Butenyl)chloropalladium dimer
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/12081-22-0.gif)
CAS
12081-22-0
Synonyms
(2-Butenyl)chloropalladium dimer, >=97%; CROTYLPALLADIUM CHLORIDE DIMER; Bis[(1,2,3-|C)-2-buten-1-yl]di-|I-chlorodi-palladiumdi-|Eth-crotylpalladium chloride; (E)-but-2-enylpalladium(II) chloride; DI-PI-CROTYLPALLADIUM CHLORIDE; (1-Methylallyl)palladium chloride dimer; Dichlorobis(1-methylallyl)dipalladium; 12081-22-0;
IUPAC Name
(E)-but-2-ene;chloropalladium(1+);
Molecular Weight
393.94g/mol
Molecular Formula
C8H14Cl2Pd2;
Canonical SMILES
CC=C[CH2-].CC=C[CH2-].Cl[Pd+].Cl[Pd+];
InChI
InChI=1S/2C4H7.2ClH.2Pd/c2*1-3-4-2;;;;/h2*3-4H,1H2,2H3;2*1H;;/q2*-1;;;2*+2/p-2/b2*4-3+;;;;;
InChI Key
ZMPSAJZWHPLTKH-HYTOEPEZSA-L;
Complexity
26.7
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
2
Exact Mass
393.855g/mol
H-Bond Acceptor
2
Heavy Atom Count
12
Monoisotopic Mass
391.854g/mol
Topological Polar Surface Area
0A^2
Application
(2-Butenyl)chloropalladium dimer serves as a versatile catalyst and reactant, primarily used in various chemical processes. It facilitates the enantioselective elimination of palladium hydride and enables the non-covalent anchoring of catalysts to silica supports. Additionally, this compound plays a critical role in the allylation of cyanoacetates and enantioselective nucleophilic substitutions. As a reactant, it is instrumental in allylic alkylation reactions and the preparation of phosphane-functionalized carbosilane dendrimers, making it an essential component in both catalytic and synthetic applications.
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