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Bromopentacarbonylmanganese(I)
PRICE INQUIRYCatalog Number
ACM14516542-2
Product Name
Bromopentacarbonylmanganese(I)
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/14516-54-2.gif)
CAS
14516-54-2
Synonyms
Bromopentacarbonylmanganese(I),Manganese pentacarbonyl bromide
IUPAC Name
carbon monoxide;manganese;bromide;
Molecular Weight
274.89
Molecular Formula
BrMn(CO)5
Canonical SMILES
[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1,OESORJHGSXJTKX-UHFFFAOYSA-M
InChI Key
OESORJHGSXJTKX-UHFFFAOYSA-M
Melting Point
2-8°C
Storage
0-6°C
Assay
0.98
Complexity
10
Covalently-Bonded Unit Count
7
EC Number
238-522-8
Exact Mass
273.831g/mol
Formal Charge
-1
H-Bond Acceptor
6
Heavy Atom Count
12
MDL Number
MFCD00049806
Monoisotopic Mass
273.831g/mol
Topological Polar Surface Area
5A^2
Application
Bromopentacarbonylmanganese(I), an orange crystalline powder, serves a critical role in synthesizing (eta6-arene)tricarbonylmanganese(I) compounds. This process involves its reaction with arenes such as hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene, and toluene, facilitated by the presence of a silver salt.
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