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Borane diphenylphosphine complex

Catalog Number
ACM41593582-2
Product Name
Borane diphenylphosphine complex
Structure
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CAS
41593-58-2
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Synonyms
Borane diphenylphosphine complex, 98%; XUFGOLYVDOBYLK-UHFFFAOYSA-N; 41593-58-2; FT-0757885; LRNNYBXLESRLOS-UHFFFAOYSA-N; diphenylphosphine-borane; MFCD00274254; diphenylphosphine borane;
IUPAC Name
boron;diphenylphosphane;
Molecular Weight
197.004g/mol
Molecular Formula
C12H11BP;
Canonical SMILES
[B].C1=CC=C(C=C1)PC2=CC=CC=C2;
InChI
InChI=1S/C12H11P.B/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;;
InChI Key
LRNNYBXLESRLOS-UHFFFAOYSA-N;
Storage
water-free area
Complexity
116
Covalently-Bonded Unit Count
2
Exact Mass
197.069g/mol
Heavy Atom Count
14
Monoisotopic Mass
197.069g/mol
Rotatable Bond Count
2
Topological Polar Surface Area
0A^2
Application
The Borane diphenylphosphine complex, appearing as a white to off-white powder or crystals, serves as a versatile reactant in various chemical processes. It is instrumental in nucleophilic addition reactions as an anion and plays a crucial role in catalytic dehydrogenation when used with ruthenium bidentate phosphine complexes. Additionally, this complex is involved in deprotonation reactions and facilitates catalytic coupling with alkynyl bromides. It is also effective in catalyst-free Staudinger ligation, an indirect method for 18F-radiolabeling. Furthermore, it aids in the preparation of chiral phosphine-phosphite bidentate ligands with a biphenyl backbone and engages in reactions with frustrated Lewis pair combinations involving group 14 triflates and sterically hindered nitrogen bases.
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