CAS 10035-06-0 Bismuth(III) nitrate pentahydrate

Synonyms

MFCD00149157; CTK0H6780; Bismuth(III) nitrate pentahydrate, 98%, for analysis; UNII-FO2ICY167B; TRA0014955; AKOS015903839; BISMUTH NITRATE PENTAHDRATE; Bismuth (III) nitrate pentahydrate; Bismuth nitrate, hydrate (1:5); I14-17605;

IUPAC Name

bismuth;trinitrate;pentahydrate;

Molecular Weight

485.067g/mol

Molecular Formula

Bi(NO3)3·5H₂O;BiH10N3O14;

Canonical SMILES

[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.[Bi+3];

InChI

InChI=1S/Bi.3NO3.5H₂O/c;3*2-1(3)4;;;;;/h;;;;5*1H2/q+3;3*-1;;;;;;

InChI Key

FBXVOTBTGXARNA-UHFFFAOYSA-N;

Complexity

18.8

Covalently-Bonded Unit Count

EC Number

600-076-0

Exact Mass

484.997g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

484.997g/mol

Topological Polar Surface Area

194A^2

UNII

FO2ICY167B

Application

Bismuth(III) nitrate pentahydrate serves as a versatile and non-toxic reagent in organic synthesis, widely valued for its easy handling and air insensitivity. This compound finds extensive use as a catalyst in various chemical reactions, such as the chemo-selective synthesis of acylals from aromatic aldehydes, one-pot synthesis of alpha-amino phosphates, and the generation of pharmaceutically functionalized piperidine derivatives. It is instrumental in protecting carbonyl compounds, facilitating Michel reactions, and acting as an excellent oxidant for 4-substituted Hantzsch 1,4-dihydropyridines and the selective oxidation of sulfides to sulfoxides. Further applications include its role in the conversion of thiocarbonyls to carbonyl compounds and the oxidative deprotection of dithioacetals when used with air as a cocatalyst. Additionally, Bismuth(III) nitrate pentahydrate is integral in the preparation of photocatalysts and other bismuth compounds, as well as being used in luminous paints and as a reagent for TLC stains, highlighting its wide range of industrial and scientific applications.

December 24, 2024

Highly Effective Reagent for Organic Synthesis Applications

Bismuth(III) nitrate pentahydrate significantly enhanced our synthesis processes. Invaluable for thiocarbonyl conversion and dithioacetal oxidation. Consistently reliable and effortless to use, it's become essential in our research projects. Highly recommended for its versatility and cost-effectiveness.