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Bis(salicylideniminato-3-propyl)methylaminocobalt(II)

Catalog Number
ACM15391249-1
Product Name
Bis(salicylideniminato-3-propyl)methylaminocobalt(II)
Structure
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CAS
15391-24-9
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Synonyms
Bis(salicylideniminato-3-propyl)methylaminocobalt(II);15391-24-9;Bis(salicylideniminato-3-propyl)methylaminocobalt( cento);Bis(salicylideniminato-3-propyl)methylaminocobalt(II), 97%;[[|A,|A inverted exclamation marka-[(Methylimino)bis(trimethylenenitrilo)]di-o-cresolato](2-)]cobalt;[[2,2 inverted exclamation marka-[(Methylimino-|EN)bis[3,1-propanediyl(nitrilo-|EN)methylidyne]]bis[phenolato-|EO]](2-)]cobalt;
IUPAC Name
cobalt;2-[3-[3-[(2-hydroxyphenyl)methylideneamino]propyl-methylamino]propyliminomethyl]phenol;
Molecular Weight
412.399g/mol
Molecular Formula
C21H27CoN3O2;
Canonical SMILES
CN(CCCN=CC1=CC=CC=C1O)CCCN=CC2=CC=CC=C2O.[Co];
InChI
InChI=1S/C21H27N3O2.Co/c1-24(14-6-12-22-16-18-8-2-4-10-20(18)25)15-7-13-23-17-19-9-3-5-11-21(19)26;/h2-5,8-11,16-17,25-26H,6-7,12-15H2,1H3;;
InChI Key
ROYMMTUICCHINZ-UHFFFAOYSA-N;
Complexity
396
Covalently-Bonded Unit Count
2
Exact Mass
412.144g/mol
H-Bond Acceptor
5
H-Bond Donor
2
Heavy Atom Count
27
Monoisotopic Mass
412.144g/mol
Topological Polar Surface Area
68.4A^2
Application
Bis(salicylideniminato-3-propyl)methylaminocobalt(II) serves as a versatile catalyst designed to facilitate a range of chemical transformations, including biomimetic coupled catalytic systems and the oxidation of para-substituted phenolics. This cobalt-Schiff base complex not only aids in allylation reactions but also promotes oxidation and oxidative cleavages, as well as the oxidative carbonylation of phenol, illustrating its multifaceted applications in synthetic chemistry.
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