CAS 3153-26-2 Bis(2,4-pentanedionato)vanadium(IV) Oxide

Synonyms

Acetylacetone Vanadium(IV)oxy Salt; Vanadyl acetylacetonate; MFCD00000032; AB1010945; C10H14O5V; Vanadyl acetylacetonate, 98%; Vanadium(IV)oxy Acetylacetonate; V0995; Vanadyl acetylacetonate, purum, >=97.0% (RT); Vanadyl acetylacetonate, 99.98% trace metals basis;

IUPAC Name

(Z)-4-hydroxypent-3-en-2-one;oxovanadium;

Molecular Weight

267.175g/mol

Molecular Formula

C10H16O5V;

Canonical SMILES

CC(=CC(=O)C)O.CC(=CC(=O)C)O.O=[V];

InChI

InChI=1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/b2*4-3-;;;

InChI Key

FSJSYDFBTIVUFD-SUKNRPLKSA-N;

Storage

Store below +30°C.

Complexity

253

Covalently-Bonded Unit Count

Defined Bond Stereocenter Count

EC Number

221-590-8

Exact Mass

267.044g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

267.044g/mol

Rotatable Bond Count

Topological Polar Surface Area

91.7A^2

Application

Bis(2,4-pentanedionato)vanadium(IV) Oxide serves as a versatile catalyst in organic chemistry and acts as an intermediary in various synthetic processes. It is instrumental in the creation of novel oxovanadium complexes that exhibit antitumor properties and proves effective as a precursor in producing vanadium dioxide thin films used in applications like "intelligent" window coatings and data storage solutions. This compound facilitates a range of reactions, including the hydroxyl-directed epoxidation of olefins, asymmetric oxidation of disulfides, the Mannich reaction, and the sulfoxidation of alkanes, highlighting its multifaceted role in chemical synthesis and industrial applications.

April 7, 2025

Exceptional Catalyst for Organic Synthesis Research

Bis(2,4-pentanedionato)vanadium(IV) Oxide from Alfa Chemistry excelled in our synthesis of oxovanadium complexes. Its role as a catalyst in olefin epoxidation and disulfide oxidation was invaluable, enhancing efficiency and outcomes remarkably.