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Bis(2,4-pentanedionato)vanadium(IV) Oxide

Catalog Number
ACM3153262-1
Product Name
Bis(2,4-pentanedionato)vanadium(IV) Oxide
Structure
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CAS
3153-26-2
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Synonyms
Acetylacetone Vanadium(IV)oxy Salt; Vanadyl acetylacetonate; MFCD00000032; AB1010945; C10H14O5V; Vanadyl acetylacetonate, 98%; Vanadium(IV)oxy Acetylacetonate; V0995; Vanadyl acetylacetonate, purum, >=97.0% (RT); Vanadyl acetylacetonate, 99.98% trace metals basis;
IUPAC Name
(Z)-4-hydroxypent-3-en-2-one;oxovanadium;
Molecular Weight
267.175g/mol
Molecular Formula
C10H16O5V;
Canonical SMILES
CC(=CC(=O)C)O.CC(=CC(=O)C)O.O=[V];
InChI
InChI=1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/b2*4-3-;;;
InChI Key
FSJSYDFBTIVUFD-SUKNRPLKSA-N;
Storage
Store below +30°C.
Complexity
253
Covalently-Bonded Unit Count
3
Defined Bond Stereocenter Count
2
EC Number
221-590-8
Exact Mass
267.044g/mol
H-Bond Acceptor
5
H-Bond Donor
2
Heavy Atom Count
16
Monoisotopic Mass
267.044g/mol
Rotatable Bond Count
2
Topological Polar Surface Area
91.7A^2
Application
Bis(2,4-pentanedionato)vanadium(IV) Oxide serves as a versatile catalyst in organic chemistry and acts as an intermediary in various synthetic processes. It is instrumental in the creation of novel oxovanadium complexes that exhibit antitumor properties and proves effective as a precursor in producing vanadium dioxide thin films used in applications like "intelligent" window coatings and data storage solutions. This compound facilitates a range of reactions, including the hydroxyl-directed epoxidation of olefins, asymmetric oxidation of disulfides, the Mannich reaction, and the sulfoxidation of alkanes, highlighting its multifaceted role in chemical synthesis and industrial applications.
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