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Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate

Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate

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Catalog Number

ACM36620118-4

Product Name

Structure

CAS

36620-11-8

Product Overview
Usage

Synonyms

36620-11-8; Bis(norbornadiene)rhodium(I) tetrafluoroborate; [rh(nbd)2]bf4; SC-49716; Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate; ANW-41403; MFCD00671775; Bis(norbornadiene)(tetrafluoroborato)rhodium; bis(norbomadiene)rhodium (I) tetrafluoroborate; Bis(norbornadiene)rhodium (I) tetrafluoroborate;

IUPAC Name

bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate;

Molecular Weight

373.991g/mol

Molecular Formula

C14H16BF4Rh-;

Canonical SMILES

[B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh];

InChI

InChI=1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;;

InChI Key

ZWPWNBFOFVFMPP-UHFFFAOYSA-N;

Storage

Refrigerator

Complexity

122

Covalently-Bonded Unit Count

Exact Mass

374.034g/mol

Formal Charge

-1

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

374.034g/mol

Topological Polar Surface Area

0A^2

Application

Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate serves as a versatile chemical compound predominantly utilized in catalytic hydrogenation and isomerization reactions. It acts as a precursor for asymmetric hydrogenation processes, facilitating the generation of chiral molecules with high specificity. This functionality makes it an indispensable tool in the synthesis of complex organic compounds, where precise molecular orientation is crucial. Its efficacy in such transformations underscores its significance in advancing research and industrial applications that demand efficient and selective catalytic processes.

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