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Bis(2-methoxyphenyl)phosphine

Catalog Number
ACM10177794-1
Product Name
Bis(2-methoxyphenyl)phosphine
CAS
10177-79-4
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Synonyms
BIS(2-METHOXYPHENYL)PHOSPHINE; TC-167749; DTXSID80470464; Di-o-anisylphosphine; Bis(2-methoxyphenyl)phosphane; 10177-79-4; AKOS015910928; Bis(2-methoxyphenyl)phosphine, 97%;
IUPAC Name
bis(2-methoxyphenyl)phosphane;
Molecular Weight
246.246g/mol
Molecular Formula
C14H15O2P;
Canonical SMILES
COC1=CC=CC=C1PC2=CC=CC=C2OC;
InChI
InChI=1S/C14H15O2P/c1-15-11-7-3-5-9-13(11)17-14-10-6-4-8-12(14)16-2/h3-10,17H,1-2H3;
InChI Key
HFEAMIKDDWKNAG-UHFFFAOYSA-N;
Complexity
200
Covalently-Bonded Unit Count
1
Exact Mass
246.081g/mol
H-Bond Acceptor
2
Heavy Atom Count
17
Monoisotopic Mass
246.081g/mol
Rotatable Bond Count
4
Topological Polar Surface Area
18.5A^2
Application
Bis(2-methoxyphenyl)phosphine serves a crucial role as a versatile reactant in various chemical syntheses and catalytic processes. It is utilized in the allylation of phenols and the formation of neutral rhodium(I) complexes, which are essential in diverse organic reactions. Additionally, it plays a key part in the synthesis of dinuclear Pd(II) complexes that contain bis-bidentate tetraphos ligands. The compound also facilitates CO-ethylene copolymerization reactions, enabling the efficient creation of polymeric materials. Moreover, bis(2-methoxyphenyl)phosphine is instrumental in the Suzuki-Miyaura reaction, aiding in the synthesis of alkyl derivatives with phosphine sulfonate (P-O) ligands, thereby broadening the scope of applications in organophosphorus chemistry.
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