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- (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
PRICE INQUIRYCatalog Number
ACM93379498-3
Product Name
(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/93379-49-8.gif)
CAS
93379-49-8
Synonyms
SCHEMBL4383952; [(4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(diphenylmethanol); AX8009294; (4S,5S)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol, 97%; AB1011168; MFCD00010079; CD-655; 379B498; KS-00000VWJ; (2S,3S)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol;
IUPAC Name
[(4S,5S)-5-[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-diphenylmethanol;
Molecular Weight
466.577g/mol
Molecular Formula
C31H30O4;
Canonical SMILES
CC1(OC(C(O1)C(C2=CC=CC=C2)(C3=CC=CC=C3)O)C(C4=CC=CC=C4)(C5=CC=CC=C5)O)C;
InChI
InChI=1S/C31H30O4/c1-29(2)34-27(30(32,23-15-7-3-8-16-23)24-17-9-4-10-18-24)28(35-29)31(33,25-19-11-5-12-20-25)26-21-13-6-14-22-26/h3-22,27-28,32-33H,1-2H3/t27-,28-/m0/s1;
InChI Key
OWVIRVJQDVCGQX-NSOVKSMOSA-N;
Complexity
574
Covalently-Bonded Unit Count
1
Defined Atom Stereocenter Count
2
Exact Mass
466.214g/mol
H-Bond Acceptor
4
H-Bond Donor
2
Heavy Atom Count
35
Monoisotopic Mass
466.214g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
58.9A^2
Application
The purpose of (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane, which appears as a white to light yellow crystalline powder, is to serve as a ligand in enantioselective reactions. It facilitates Lewis-acid mediated Diels-Alder reactions, allyltitanation of aldehydes, and Michael-Mukaiyama additions, all promoted by chiral titanium complexes.
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