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Bis(2-furyl)phosphine chloride

Catalog Number
ACM181257352-1
Product Name
Bis(2-furyl)phosphine chloride
CAS
181257-35-2
  • Product Overview
  • Usage
Synonyms
FCH1325675; MFCD01630851; Di-2-furanylphosphinous chloride; chlorodifuran-2-ylphosphine; Bis(2-furyl)phosphine chloride, 85%; DTXSID30408373; BIS(2-FURYL)CHLOROPHOSPHINE; 181257-35-2; AKOS015910836; Chlorodi(2-furyl)phosphine;
IUPAC Name
chloro-bis(furan-2-yl)phosphane;
Molecular Weight
200.558g/mol
Molecular Formula
C8H6ClO2P;
Canonical SMILES
C1=COC(=C1)P(C2=CC=CO2)Cl;
InChI
InChI=1S/C8H6ClO2P/c9-12(7-3-1-5-10-7)8-4-2-6-11-8/h1-6H;
InChI Key
IYEUYNXDXNWPJI-UHFFFAOYSA-N;
Complexity
140
Covalently-Bonded Unit Count
1
Exact Mass
199.979g/mol
H-Bond Acceptor
2
Heavy Atom Count
12
Monoisotopic Mass
199.979g/mol
Rotatable Bond Count
2
Topological Polar Surface Area
26.3A^2
Application
Bis(2-furyl)phosphine chloride serves as a versatile reactant in the synthesis of various complex chemical compounds and reactions. Its primary purpose includes the development of centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands and ferrocene-based chiral diphosphine compounds, which are crucial in creating chirally enriched environments for catalytic processes. Additionally, it facilitates the formation of phosphine-containing amino acids, enhancing the functional diversity of amino acid derivatives. This compound also plays a significant role in the α-arylation of aldehydes, allowing for the formation of diverse aryl structures. Moreover, it supports stereoselective [2,3] sigmatropic rearrangements of acyclic allylic phosphinites, crucial for configuring complex stereochemistry, and aids in the hydrophosphination of functionalized alkenes, contributing to the formation of phosphorus-carbon bonds in functionalized organic molecules.
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