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[1,1'-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

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Catalog Number

ACM917511901-2

Product Name

Structure

CAS

917511-90-1

Product Overview
Usage

Synonyms

PdCl2(dcypf)

IUPAC Name

dichloropalladium;dicyclohexyl(cyclopentyl)phosphane;iron

Molecular Weight

755.90

Molecular Formula

C₃₄H₅₂Cl₂FeP₂Pd

Canonical SMILES

C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.Cl[Pd]Cl.[Fe]

InChI Key

HRAMBTUEZQOQRK-UHFFFAOYSA-L

Melting Point

294-300ºC

Purity

Pd >14.0%

Appearance

red crystalline powder

Exact Mass

754.13100

MDL Number

MFCD11656081

Application

[1,1'-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) serves as an air-stable catalyst designed to facilitate key reactions in organic synthesis. This catalyst is particularly effective in the arylation of ketones using aryl chlorides and aryl bromides, enabling the formation of α-aryl carbonyl compounds. Additionally, it is instrumental in the synthesis of α, β-unsaturated amides through the hydroaminocarbonylation of alkynes with tertiary amines. It also supports the creation of quinazoline derivatives through the Suzuki-Miyaura coupling reaction, even in the presence of unprotected NH2 groups in quinazolines and arylboronic acids. This multifaceted utility makes it an invaluable tool in advancing synthetic methodology.

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917511-90-1
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Pd >14.0%
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