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Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

Catalog Number
ACM130296285-1
Product Name
Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate
Structure
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CAS
130296-28-5
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Synonyms
Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate;130296-28-5;MFCD11113031;CTK8E6926;RT-011523;
IUPAC Name
cycloocta-1,5-diene;hexafluoroantimony(1-);rhodium;
Molecular Weight
555.024g/mol
Molecular Formula
C16H24F6RhSb-;
Canonical SMILES
C1CC=CCCC=C1.C1CC=CCCC=C1.F[Sb-](F)(F)(F)(F)F.[Rh];
InChI
InChI=1S/2C8H12.6FH.Rh.Sb/c2*1-2-4-6-8-7-5-3-1;;;;;;;;/h2*1-2,7-8H,3-6H2;6*1H;;/q;;;;;;;;;+5/p-6;
InChI Key
ZSPLJWNAXJRVRK-UHFFFAOYSA-H;
Complexity
135
Covalently-Bonded Unit Count
4
Exact Mass
553.988g/mol
Formal Charge
-1
H-Bond Acceptor
7
Heavy Atom Count
24
Monoisotopic Mass
553.988g/mol
Topological Polar Surface Area
0A^2
Undefined Bond Stereocenter Count
4
Application
Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate, characterized by its distinctive brown crystal form, serves as a catalyst primarily used in the [3+2] cycloaddition process. It plays a significant role in the synthesis of diastereomeric chiral phosphorus monodentate and bidentate diamidophosphite ligands, which are derived from dianhydromannitol. These ligands are essential in asymmetric metallocomplex catalysis, facilitating various chemical transformations, including C-C bond-forming hydrogenation, thereby contributing to advancements in organic synthesis and catalysis.
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