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Bis(benzonitrile)dichloropalladium(II)

Catalog Number
ACM14220645-2
Product Name
Bis(benzonitrile)dichloropalladium(II)
Structure
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CAS
14220-64-5
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Molecular Weight
383.57
Molecular Formula
C14H10N2Cl2Pd
Purity
Metal purity 99.95
Appearance
yellow orange
Color Form
powder
Empirical Formula
[Pd(C6H5CN)2Cl2]
Metal Content
27
Application
Bis(benzonitrile)dichloropalladium(II) serves as a versatile and highly efficient catalyst, facilitating a wide range of chemical reactions with an emphasis on sustainability and enhanced catalytic performance. Its applications are diverse, including its role as a catalyst in greener amine synthesis from terminal olefins through Wacker oxidation, followed by transfer hydrogenation of the resultant imine. It is also instrumental in the cyclization of δ-acetylenic carboxylic acids to form butenolides, and it enables the aza-Michael reaction of carbamates with enones. Furthermore, this catalyst aids in the rearrangement of allylic imidates to allylic amides, the Nazarov cyclization of α-alkoxy dienones, and the diamination of conjugated dienes. It is particularly effective in three-component Michael addition, cyclization, cross-coupling reactions, and the C-H activation of indoles. Additionally, it supports formal anti-Markovnikov hydroamination of terminal olefins, demonstrating its broad applicability in modern synthesis and its contribution to more environmentally friendly chemical processes.
February 9, 2025

A Versatile Catalyst for Modern Chemistry

Bis(benzonitrile)dichloropalladium(II) is excellent in various reactions, especially the Suzuki coupling. Its high efficiency enhanced our synthesis of amines and facilitated our cyclization processes with minimal environmental impact.

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