Molecular Weight
1436.73
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Berkessel-Katsuki epoxidation catalyst
Catalog Number
ACM2055468238
Product Name
Berkessel-Katsuki epoxidation catalyst
CAS
2055468-23-8
Application
The Berkessel-Katsuki epoxidation catalyst is designed to streamline and enhance the production of enantiopure epoxides, serving as a crucial tool in synthesizing bioactive compounds. Developed in Albrecht Berkessel's lab, this innovative catalyst enables the enantioselective epoxidation of non-conjugated terminal double bonds using hydrogen peroxide as an oxidant. By eliminating the need for multiple steps and kinetic resolution, it offers a single-step process via a pre-formed chiral ligand-Ti2O2 catalyst complex. Additionally, the catalyst can be reused under specific conditions, making it a sustainable choice. To optimize its performance, pairing it with co-catalysts such as pentafluorobenzoic acid (P5360) or tetra-n-butylammonium hydrogensulfate (155837) is advised.
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