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Benzoylferrocene

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Catalog Number

ACM1272442

Product Name

Benzoylferrocene

Structure

CAS

1272-44-2

Product Overview
Usage

Synonyms

Ferrocenyl(phenyl)methanone, (Benzoylcyclopentadienyl)cyclopentadienyliron, Ferrocenyl phenyl ketone, Ferrecenophenone

Molecular Weight

290.14

Molecular Formula

C17H14FeO

Canonical SMILES

[Fe].[CH]1[CH][CH][CH][CH]1.O=C([C]2[CH][CH][CH][CH]2)c3ccccc3

InChI

1S/C12H9O.C5H5.Fe/c13-12(11-8-4-5-9-11)10-6-2-1-3-7-10;1-2-4-5-3-1;/h1-9H;1-5H;

InChI Key

JJHHJZCYDPLHIL-UHFFFAOYSA-N

Melting Point

105-107 °C (lit.)

Purity

≥98%

Appearance

Solid

Application

Benzoylferrocene is a versatile red to red-brown powder used as an intermediate in various chemical processes. It serves as a reactant in several key reactions, including the deprotonative metalation of ferrocenes, oxidative chemistry, and the reduction of ferrocenyl ketones. Additionally, it is involved in the polymerization of C-ferrocenyl-substituted phosphaalkenes. Benzoylferrocene is also crucial for the synthesis of complex molecules such as planar chiral triferrocenylmethane derivatives and chiral ferrocenyl alcohols, which can be achieved via asymmetric transfer hydrogenation.

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CAS
Size
Purity
Price
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1272-44-2
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≥98%
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