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(+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)

(+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)

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Catalog Number

ACM112246738-1

Product Name

Structure

CAS

112246-73-8

Product Overview
Usage

Synonyms

chloranyl-bis[(1R,3S,4R,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane; AS-47257; (+)-diisopinocampheyl chloroborane, 60%-65% in hexanes; chloro-bis[(1R,3S,4R,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane; FT-0082537; Q-101079; (+)-DIP chloride; 112246-73-8; BP-10075; PubChem8146;

IUPAC Name

chloro-bis[(1R,2R,3S,5R)-2,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane;

Molecular Weight

320.752g/mol

Molecular Formula

C20H34BCl;

Canonical SMILES

B(C1CC2CC(C1C)C2(C)C)(C3CC4CC(C3C)C4(C)C)Cl;

InChI

InChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13-,14-,15+,16+,17-,18-/m0/s1;

InChI Key

PSEHHVRCDVOTID-YYNWCRCSSA-N;

Storage

2-8°C

Complexity

428

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Exact Mass

320.244g/mol

Heavy Atom Count

Monoisotopic Mass

320.244g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2

Application

(+)-B-Chlorodiisopinocampheylborane, in a concentration of about 1.6 mol/L in hexane, serves a crucial role in synthetic chemistry. It is designed specifically for the asymmetric reduction of prochiral ketones, facilitating the production of compounds with high enantiomeric purity. Additionally, this reagent is instrumental in the preparation of β-amino alcohols, which are valuable intermediates in various chemical synthesis processes.

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