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Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)

Catalog Number
ACM478980039-3
Product Name
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)
Structure
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CAS
478980-03-9
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Synonyms
Palladium, [1, 3- bis[2, 6- bis(1- methylethyl) phenyl] - 1, 3- dihydro- 2H- imidazol- 2- ylidene] chloro(η3- 2- propen- 1- yl) -
Molecular Weight
572.54
Molecular Formula
C30H42ClN2Pd
Melting Point
> 300 °C (> 572 °F)
Purity
98%, Pd>18.5%
Appearance
white solid
MDL Number
MFCD08561131
Symbol
GHS07
Application
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) serves as a versatile yellow crystal catalyst with multiple applications in chemical reactions. It is particularly effective in facilitating the arylation of ketones, Suzuki coupling, and Buchwald-Hartwig amination reactions. This air-stable, well-defined palladium N-heterocyclic carbene complex also excels in the dehalogenation of aryl chlorides, oxidation of secondary alcohols, and cross-coupling of aryl chlorides with boronic acids. Additionally, it acts as a catalyst for the diamination of conjugated dienes and trienes, promotes anaerobic alcohol and ketone oxidation, and enables domino oxidation/α-arylation processes.
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