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5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol

Catalog Number
ACM101203310
Product Name
5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol
Structure
5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol
CAS
101203-31-0
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Synonyms
BIPHEN-H2; FT-0767390; (S)-(-)-3,3'-Di-tert-butyl-5,5',6,6'-tetramethylbiphenyl-2,2'-diol; (S)-(-)-5,5 inverted exclamation marka,6,6 inverted exclamation marka-Tetramethyl-3,3 inverted exclamation marka-di-tert-butyl-1,1 inverted exclamation marka-biphenyl-2,2 inverted exclamation marka-diol; 5,5',6,6'-Tetramethyl-3,3'-di-tert-butyl-1,1'-biphenyl-2,2'-diol, 97%; (R)-(+)-5,5',6,6'-TETRAMETHYL-3,3'-DI-T-BUTYL-1,1'- BIPHENYL-2,2'-DIOL, 99% (R)-BIPHEN H2; FT-0710826; (S)-()-5,5,6,6-Tetramethyl-3,3-di-tert-butyl-1,1-biphenyl-2,2-diol; AKOS015910403; Acm³29735684;
IUPAC Name
6-tert-butyl-2-(3-tert-butyl-2-hydroxy-5,6-dimethylphenyl)-3,4-dimethylphenol;
Molecular Weight
354.534g/mol
Molecular Formula
C24H34O2;
InChI
InChI=1S/C24H34O2/c1-13-11-17(23(5,6)7)21(25)19(15(13)3)20-16(4)14(2)12-18(22(20)26)24(8,9)10/h11-12,25-26H,1-10H3;
InChI Key
NMVVBVMYPLMIOU-UHFFFAOYSA-N;
Complexity
428
Covalently-Bonded Unit Count
1
Exact Mass
354.256g/mol
H-Bond Acceptor
2
H-Bond Donor
2
Heavy Atom Count
26
Monoisotopic Mass
354.256g/mol
Rotatable Bond Count
3
Topological Polar Surface Area
40.5A^2
Application
Used as a ligand backbone for metathesis catalysts.

2. Used as a ligand backbone in catalytic asymmetric hydrogenation.

3. Used as a ligand backbone for asymmetric hydroformylation of allyl cyanide.

4. Used as a ligand backbone for phosphoramidite ligands in the asymmetric

Rh-catalyzed [2+2+2] cycloaddition.

5. Used as a ligand backbone for the ring-opening polymerization of cyclic esters.
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