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- (4R,5R)-1,3-Dimethyl-4,5-diphenyl-2-[(S)-1-benzyl-2-hydroxyethylimino]imidazolidine
(4R,5R)-1,3-Dimethyl-4,5-diphenyl-2-[(S)-1-benzyl-2-hydroxyethylimino]imidazolidine
PRICE INQUIRYCatalog Number
ACM337308631-1
Product Name
(4R,5R)-1,3-Dimethyl-4,5-diphenyl-2-[(S)-1-benzyl-2-hydroxyethylimino]imidazolidine
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/337308-63-1.gif)
CAS
337308-63-1
Synonyms
AKOS015850666; (4R,5R)-1,3-DIMETHYL-4,5-DIPHENYL-2-[(S)-1-BENZYL-2-HYDROXYETHYLIMIDAZOLIDINE; ANW-27685; (S)-2-(((4R,5R)-1,3-Dimethyl-4,5-diphenylimidazolidin-2-ylidene)amino)-3-phenylpropan-1-ol; SCHEMBL12952591; ( )-Chiba G; (4R,5R)-1,3-Dimethyl-4,5-diphenyl-2-[(S)-1-benzyl-2-hydroxyethylimino]imidazolidine; 337308-63-1; (4r,5r)-1,3-dimethyl-4,5-diphenyl-2-[(s)-1-hydroxymethyl-2-phenylethylimino]imidazolidine;
IUPAC Name
(2S)-2-[[(4R,5R)-1,3-dimethyl-4,5-diphenylimidazolidin-2-ylidene]amino]-3-phenylpropan-1-ol;
Molecular Weight
399.538g/mol
Molecular Formula
C26H29N3O;
Canonical SMILES
CN1C(C(N(C1=NC(CC2=CC=CC=C2)CO)C)C3=CC=CC=C3)C4=CC=CC=C4;
InChI
InChI=1S/C26H29N3O/c1-28-24(21-14-8-4-9-15-21)25(22-16-10-5-11-17-22)29(2)26(28)27-23(19-30)18-20-12-6-3-7-13-20/h3-17,23-25,30H,18-19H2,1-2H3/t23-,24+,25+/m0/s1;
InChI Key
RAFFEHDNCQXIQG-ISJGIBHGSA-N;
Complexity
515
Covalently-Bonded Unit Count
1
Defined Atom Stereocenter Count
3
Exact Mass
399.231g/mol
H-Bond Acceptor
2
H-Bond Donor
1
Heavy Atom Count
30
Monoisotopic Mass
399.231g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
39.1A^2
Application
The purpose of (4R,5R)-1,3-Dimethyl-4,5-diphenyl-2-[(S)-1-benzyl-2-hydroxyethylimino]imidazolidine is to facilitate the stereoselective preparation of trisubstituted cyclohexanols. This is achieved through a tandem Henry-Michael reaction of nitromethane with 7-oxo-5-heptenals, utilizing tetramethylguanidine or a chiral guanidine organocatalyst.
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