CONTACT US

Tel:
Fax:
Address:
Email: For product inquiries or a copy of our product catalog, please use our online system or send an email to .

chemistry partner

(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene

Catalog Number
ACM71042541-2
Product Name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
Structure
{[CurrentData.Name]}
CAS
71042-54-1
  • Product Overview
  • Usage
Synonyms
71042-54-1;(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE;(+)-Norphos;(2S,3S)-(+)-2,3-bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene;SCHEMBL12446363;ZINC2575216;MFCD00085364;BP-12263;(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE, MIN. 95% (S,S)-NORPHOS;
IUPAC Name
[(1R,2S,3S,4S)-3-diphenylphosphanyl-2-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane;
Molecular Weight
462.513g/mol
Molecular Formula
C31H28P2;
Canonical SMILES
C1C2C=CC1C(C2P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6;
InChI
InChI=1S/C31H28P2/c1-5-13-26(14-6-1)32(27-15-7-2-8-16-27)30-24-21-22-25(23-24)31(30)33(28-17-9-3-10-18-28)29-19-11-4-12-20-29/h1-22,24-25,30-31H,23H2/t24-,25+,30-,31-/m0/s1;
InChI Key
CDJHPMXMJUCLPA-QHNMYUOLSA-N;
Complexity
543
Covalently-Bonded Unit Count
1
Defined Atom Stereocenter Count
4
Exact Mass
462.167g/mol
Heavy Atom Count
33
Monoisotopic Mass
462.167g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
0A^2
Application
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene is a white crystalline powder that serves as a ligand in various enantioselective rhodium-catalyzed reactions. Its primary applications include the hydrogenation of α-dehydroaminoesters and enamides, the hydroboration of cyclopropenes, and the asymmetric cleavage of racemic 1,3-oxazolidines. This ligand facilitates these processes by enhancing stereoselectivity, making it a valuable component in asymmetric synthesis.
If you have any other questions or need other size, please get a quote.
  • CAS
  • Size
  • Purity
  • Price
  • Quantity
  • Order
※ Please kindly note that our products are for research use only.

Share

Interested in our Services & Products? Need detailed information?
facebook twitter linkedin

Contact us

Email:
Tel:
Fax:
Address: