CAS 863971-62-4 [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)

Synonyms

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);863971-62-4;

IUPAC Name

chlororuthenium;N-[[6-(ditert-butylphosphanylmethyl)pyridin-2-yl]methyl]-N-ethylethanamine;formaldehyde;

Molecular Weight

489.023g/mol

Molecular Formula

C20H37ClN2OPRu;

Canonical SMILES

CCN(CC)CC1=NC(=CC=C1)CP(C(C)(C)C)C(C)(C)C.C=O.Cl[Ru];

InChI

InChI=1S/C19H35N2P.CH₂O.ClH.Ru/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;/h11-13H,9-10,14-15H2,1-8H3;1H2;1H;/q;;;+1/p-1;

InChI Key

XHYRMHCSCCPWAZ-UHFFFAOYSA-M;

Complexity

302

Covalently-Bonded Unit Count

Exact Mass

489.138g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

489.138g/mol

Rotatable Bond Count

Topological Polar Surface Area

33.2A^2

MSDS

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COA

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Spec Sheet

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Application

Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.

Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.

Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.

Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.

Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone