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2,2'-Bipyridyl

Catalog Number
ACM366187-1
Product Name
2,2'-Bipyridyl
Structure
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CAS
366-18-7
  • Product Overview
  • Usage
Description
2,2'-Bipyridyl also known as 2,2'-bipyridine, is a symmetrical bipyridine commonly used as a neutral ligand for chelating with metal ions. A study of its impact on Petunia hybrida flowers showed that it caused inhibition of senescence.
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Synonyms
2,2'-Dipyridyl, 2,2'-Dipyridine, 2,2'-Bipyridine
IUPAC Name
2-pyridin-2-ylpyridine
Molecular Weight
156.18
Molecular Formula
C10H8N2
Canonical SMILES
c1ccc(nc1)-c2ccccn2
InChI
1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H
InChI Key
ROFVEXUMMXZLPA-UHFFFAOYSA-N
Boiling Point
273 °C (lit.)
Melting Point
70-73 °C (lit.)
Flash Point
Not applicable
Purity
0.99
Solubility
0.04 M;Very sol in alcohol, ether, and benzene;Soluble in oxygenated solvents;In water, 5.93X10+3 mg/l @ 25 °C;Solubility in water, g/100ml: 6.4
Appearance
White to Almost white powder to crystal
Storage
Store under inert gas
Assay
≥99%
Color Form
White crystals;Crystals from dilute alcohol;PRISMS FROM PETROLEUM ETHER
Complexity
120
Covalently-Bonded Unit Count
1
Decomposition
When heated to decomposition it emits toxic fumes of /nitrogen oxides/.
EC Number
206-674-4
Exact Mass
156.068748g/mol
Formal Charge
0
H-Bond Acceptor
2
H-Bond Donor
0
Heavy Atom Count
12
ICSC Number
0093
LogP
1.5 (LogP);log Kow= 1.50
MDL Number
MFCD00006212
MeSH Entry Terms
2,2 Bipyridine;2,2 Bipyridyl;2,2 Dipyridyl;2,2' Bipyridine;2,2' Dipyridyl;2,2'-Bipyridine;2,2'-Dipyridyl;2,2-Bipyridine;2,2-Bipyridyl;2,2-Dipyridyl;alpha,alpha Dipyridyl;alpha,alpha-Dipyridyl;Bipyridyl;Dipyridyl, 2,2;Dipyridyl, 2,2'
Monoisotopic Mass
156.068748g/mol
NSC Number
615009;1550
Refractive Index
1.62
Rotatable Bond Count
1
RTECS Number
DW1750000
UNII
551W113ZEP
Application
Ligand for copper in greener oxidation of alcohols under aerobic conditions.
2,2'-Bipyridyl has been used in the preparation of copper(II)-bipyridine-naringenin complex. It may be used in the preparation of 2,2'-bipyridyl hydrobromide.
Bidentate ligand employed in transition metal catalysis and aluminum initiated polymerization (inorganic syntheses).
Ligand for copper in greener oxidation of alcohols under aerobic conditions.
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
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