Molecular Weight
1009.70
Molecular Formula
C34H18F16IrN4P
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- (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Catalog Number
ACM1092775626
Product Name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Structure
![{[CurrentData.Name]}](https://resource.alfachemic.com/structure/1092775-62-6.gif)
CAS
1092775-62-6
Application
The product, (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%, serves as a versatile photoredox catalyst, particularly when used in conjunction with a nickel catalyst. It facilitates the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under mild conditions, proving effective in various applications. Its capabilities extend to the chemo-, regio-, and stereoselective trifluoromethylation of styrene. Additionally, this catalyst is instrumental in the synthesis of benzylic ethers through Ir/Ni dual catalysis, in catalytic olefin hydroamidation via proton-coupled electron transfer, and in the visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates. It also supports photoredox/nickel dual catalytic cross-coupling involving secondary alkyl β-trifluoroboratoketones and esters with aryl bromides, as well as the cross-coupling of trifluoroalkylboranes.
February 17, 2025
Exceptional Photoredox Catalyst for Advanced Research
After incorporating this iridium complex in our study, its efficiency in photoredox/nickel dual catalysis impressed us. Seamlessly facilitated C-sp3 cross-couplings under mild conditions, enhancing our research outcomes significantly. Highly recommended for intricate chemical synthesis projects.
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