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(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane

Catalog Number
ACM74663755-2
Product Name
(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane
Structure
(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane
CAS
74663-75-5
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Synonyms
N,N'-Bis(2,6-diisopropylphenyl)-1,4-diazabutadiene; N,N'-Bis(2,6-diisopropylphenyl)ethanediimine; Glyoxal bis(2,6-diisopropylanil)
IUPAC Name
N,N'-bis[2,6-di(propan-2-yl)phenyl]ethane-1,2-diimine;
Molecular Weight
376.58
Molecular Formula
C₂₆H₃₆N₂
InChI
InChI=1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3;
InChI Key
JWVIIGXMTONOFR-UHFFFAOYSA-N;
Melting Point
105-109° C
Storage
room temperature
Complexity
425
Covalently-Bonded Unit Count
1
Exact Mass
376.288g/mol
H-Bond Acceptor
2
Heavy Atom Count
28
Monoisotopic Mass
376.288g/mol
Rotatable Bond Count
7
Topological Polar Surface Area
24.7A^2
Application
Reactant in preparation of derived ruthenium olefin metathesis catalysts 1 N-cyclic carbene ligand 2 Catalyst in: Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands 3 Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors 4 N-arylation of aromatic amines 5 Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions.
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