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(11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

(11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

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Catalog Number

ACM695162868

Product Name

CAS

695162-86-8

Product Overview
Reviews

Synonyms

2,6-Diphenyl-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide; (11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee); Phosphoric acid (aS)-3,3'-diphenyl-1,1'-binaphthalene-2,2'-diyl ester; (aR)-2,6-Diphenyl-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide; 1,1'-Bi(3-phenylnaphthalene)-2,2'-diol 2,2'-phosphate; J3.493.237I; MFCD17676194; (11bR)-4-Hydroxy-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide; (aS)-2,6-Diphenyl-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide; NCGC00161025-02;

IUPAC Name

13-hydroxy-10,16-diphenyl-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide;

Molecular Weight

500.49g/mol

Molecular Formula

C32H21O4P;

Canonical SMILES

C1=CC=C(C=C1)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=CC=CC=C7)O;

InChI

InChI=1S/C32H21O4P/c33-37(34)35-31-27(21-11-3-1-4-12-21)19-23-15-7-9-17-25(23)29(31)30-26-18-10-8-16-24(26)20-28(32(30)36-37)22-13-5-2-6-14-22/h1-20H,(H,33,34);

InChI Key

RLPAIZCRXBEKDM-UHFFFAOYSA-N;

Complexity

771

Covalently-Bonded Unit Count

Exact Mass

500.118g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

500.118g/mol

Rotatable Bond Count

Topological Polar Surface Area

55.8A^2

April 6, 2023

Good application in chiral catalysis experiments

(11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee) can be used as a chiral catalyst to catalyze the synthesis of chiral products with high enantioselectivity.

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