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(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%

(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%

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Catalog Number

ACM1372719931

Product Name

Structure

CAS

1372719-93-1

Product Overview
Usage
Reviews

Synonyms

1372719-93-1;MFCD29905021;MFCD29905022;1585988-92-6;7,7'-(Phosphinicodioxy)-6,6'-bis(9-phenanthrenyl)-1,1'-spirobiindan;(aR)-6,6'-Di(9-phenanthryl)-7,7'-(hydroxyphosphinylidenebisoxy)-1,1'-spirobiindan;Phosphoric acid [(aS)-6,6'-di(9-phenanthryl)-1,1'-spirobiindan-7,7'-diyl] ester;(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin;(11aS)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin;

IUPAC Name

12-hydroxy-1,10-di(phenanthren-9-yl)-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide;

Molecular Weight

666.713g/mol

Molecular Formula

C45H31O4P;

Canonical SMILES

C1CC23CCC4=C2C(=C(C=C4)C5=CC6=CC=CC=C6C7=CC=CC=C75)OP(=O)(OC8=C(C=CC1=C38)C9=CC1=CC=CC=C1C1=CC=CC=C19)O;

InChI

InChI=1S/C45H31O4P/c46-50(47)48-43-37(39-25-29-9-1-3-11-31(29)33-13-5-7-15-35(33)39)19-17-27-21-23-45(41(27)43)24-22-28-18-20-38(44(49-50)42(28)45)40-26-30-10-2-4-12-32(30)34-14-6-8-16-36(34)40/h1-20,25-26H,21-24H2,(H,46,47);

InChI Key

GMCOBEDKNDREBU-UHFFFAOYSA-N;

Complexity

1220

Covalently-Bonded Unit Count

Exact Mass

666.196g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

666.196g/mol

Rotatable Bond Count

Topological Polar Surface Area

55.8A^2

Application

(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%, is designed to facilitate the enantioselective construction of complex molecular frameworks, such as dibenzo[1,4]diazepine and cyclopenta[1,4]diazepine, through catalytic asymmetric reactions. By leveraging its unique chiral spiro-phosphoric acid structure, this product effectively promotes diastereo and enantioselective synthesis, enabling precise assembly of pyrrolobenzo-1,4-diazine skeletons with quaternary stereocenters. Its application in catalytic asymmetric homo-1,3-dipolar cycloadditions of azomethine ylides specifically aids in producing imidazolidines with significant stereochemical control and biological relevance.

April 16, 2025

Highly Pure and Effective for Research Needs

I've used Alfa Chemistry's (11aR)-10,11,12,13-Tetrahydro compound in synthesizing imidazolidines through catalytic asymmetric cycloadditions. Its minimum 98% purity ensured the diastereo and enantioselectivity critical for my research's success.

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