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Ruthenium Catalysts
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)

1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)

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Catalog Number

ACM104439772-1

Product Name

Structure

CAS

104439-77-2

Product Overview
Documentation
Usage

Synonyms

Shvo's catalyst

Molecular Weight

1084.1

Molecular Formula

C62H41O6Ru2

InChI

InChI=1S/C29H21O.C29H20O.4CO.2Ru/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;/h1-20,30H;1-20H;

InChI Key

LYADOKFHMFDLJK-UHFFFAOYSA-N

Melting Point

223-227 °C

Purity

98%

Appearance

Powder

Exact Mass

1087.10008

Monoisotopic Mass

1085.098995

Rotatable Bond Count

Topological Polar Surface Area

41.3 Å²

MSDS

Download MSDS

COA

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Spec Sheet

Download Spec Sheet

Application

In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral acetates.

Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.

Conversion of secondary amines to primary amines in the presence of ammonia.

Co-catalyt for aerobic lactonization of diols.

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