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1,1'-Bis(diphenylphosphino)ferrocene

Catalog Number
ACM12150468-1
Product Name
1,1'-Bis(diphenylphosphino)ferrocene
Structure
1,1'-Bis(diphenylphosphino)ferrocene
CAS
12150-46-8
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Synonyms
1,1'-Ferrocenediyl-bis(diphenylphosphine); DPPF
IUPAC Name
1,1-Bis(diphenylphosphino)ferrocene
Molecular Weight
554.38
Molecular Formula
C34H28FeP2
Boiling Point
363.8ºC at 760mmHg
Melting Point
181-182 °C(dec.)(lit.)
Flash Point
182.8ºC
Purity
98%
Appearance
Solid
Storage
2-8°C
Exact Mass
554.10200
Stability
Stable. Incompatible with strong oxidizing agents.
Application
Ligand for Pd-catalyzed cross-coupling.

Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.

Ligand for Ni-catalyzed amination of aryl chlorides.

Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.

Ligand for Ni-catalyzed Suzuki reactions.

Ni-catalyzed hydroamination of 1,3-dienes.

Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.

Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.

Ligand for Ru-catalyzed reduction of nitriles to primary amines.

Ligand for Rh-catalyzed alkyne head-to-tail dimerization.

Ligand for Rh-catalyzed cross-coupling

Ligand for Rh-catalyzed olefin isomerization

Ligand for Ni or Rh-catalyzed borylation

Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.
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