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Hexarhodium(0) hexadecacarbonyl

Catalog Number
ACM28407514-2
Product Name
Hexarhodium(0) hexadecacarbonyl
Structure
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CAS
28407-51-4
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Synonyms
Rhodium, tetra-m3-carbonyldodecacarbonylhexa-,octahedro; Hexarhodium hexadecacarbonyl; SZQABOJVTZVBHE-UHFFFAOYSA-N; HEXARHODIUMHEXADECACARBONYL; Rhodium(0) carbonyl; HEXADECACARBONYLHEXARHODIUM; RL02967; Hexarhodium(0) hexadecacarbonyl, Rh 57-60 % (approx.);
IUPAC Name
carbon monoxide;rhodium;
Molecular Weight
1065.593g/mol
Molecular Formula
Rh6(CO)16;C16O16Rh6;
Canonical SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Rh].[Rh].[Rh].[Rh].[Rh].[Rh];
InChI
InChI=1S/16CO.6Rh/c16*1-2;;;;;;;
InChI Key
SZQABOJVTZVBHE-UHFFFAOYSA-N;
Complexity
10
Covalently-Bonded Unit Count
22
EC Number
249-009-3
Exact Mass
1065.352g/mol
H-Bond Acceptor
16
Heavy Atom Count
38
Monoisotopic Mass
1065.352g/mol
Topological Polar Surface Area
16A^2
Application
Hexarhodium(0) hexadecacarbonyl serves a pivotal role as a versatile catalyst due to its unique cluster structure and black crystal form. It is extensively utilized in the hydrogenation of alkenes and the hydroformylation of alkenes, making it invaluable to various industrial processes. Additionally, this compound functions as a reducing agent for aldehydes, ketones, and nitro groups, and it catalyzes carbenoid reactions of diazo compounds.
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