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(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh

Catalog Number
ACM78355596
Product Name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh
Structure
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh
CAS
78355-59-6
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Synonyms
MFCD09839138;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh;78355-59-6;
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;[(1R,2S,3S,4S)-3-diphenylphosphanyl-2-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane;rhodium;tetrafluoroborate;
Molecular Weight
760.406g/mol
Molecular Formula
C39H40BF4P2Rh-;
InChI
InChI=1S/C31H28P2.C8H12.BF4.Rh/c1-5-13-26(14-6-1)32(27-15-7-2-8-16-27)30-24-21-22-25(23-24)31(30)33(28-17-9-3-10-18-28)29-19-11-4-12-20-29;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-22,24-25,30-31H,23H2;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t24-,25+,30-,31-;;;/m0.../s1;
InChI Key
DPXNIIPVFLWYAU-KCRFXNLBSA-N;
Complexity
635
Covalently-Bonded Unit Count
4
Defined Atom Stereocenter Count
4
Defined Bond Stereocenter Count
2
Exact Mass
760.169g/mol
Formal Charge
-1
H-Bond Acceptor
5
Heavy Atom Count
47
Monoisotopic Mass
760.169g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
0A^2
Application
Ligand used in the enantioselective rhodium catalyzed hydrogenation of α-dehydroaminoesters and enamides.

Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.

Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
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